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Controlling morphology, adopting metal cations and introducing crystal water are three effective strategies to improve the electrochemical performance of various battery electrodes. However, the effects of simultaneously applying these three strategies to aqueous rechargeable zinc batteries (ARZBs) are rarely demonstrated. Herein, hierarchical H11 Al2 V6 O23.2 (HAVO) microspheres were successfully prepared using a simple hydrothermal method, and used as cathode material for ARZBs. The as-prepared HAVO microspheres exhibited superior ele