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Further experiments with methyl phenyl sulfoxide (PMSO) as the probe indicated that Cl- would facilitate the shift of reactive species from Fe(IV) to radicals (SO4·- or ·OH) in the system. Both hydroxylation and nitration intermediate products were detected in the oxidation of DMP. Cl- promoted the formation of hydroxylation intermediates and reduced the formation of nitration intermediates. This study revealed for the first time that Cl- could shift reactive species from Fe(IV) to radicals in PMS/Fe(II) system, raising attention to the influence of the coe
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