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g-1). In addition, grand canonical Monte Carlo simulation is conducted. The micropores and mesopores created after microbial pretreatment are effective toluene adsorption sites. Moreover, the diffusion coefficient calculated by utilizing Thomas model and Chemical diffusion verify that the mesopores accelerate the kinetic process of toluene adsorption. A facile and cost effective acid leaching-coprecipitation method was developed to prepare spinel-type (Mg,Ni)(Fe,Al)2O4 from saprolite laterite ore in large scale. The as-prepare