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Boosting photocatalytic performance via external fields is an alternative and effective solution for improving the application performance of existing photocatalysts. Herein, using α-Fe2O3-decorated TiO2 nanotube arrays as a model, we demonstrate the influence of magnetic field (MF)-direction on the photogenerated charge-carrier transfer behavior at plasmonic metal/semiconductor interfaces. For the first time, the photocatalytic activity is also found to correlate with the plasmonic metal species while applying an external MF. As verifie