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Upon near-infrared (NIR) light visibility, this concept of polymerization is named photoinduced thermal polymerization or photothermal polymerization. Many thanks to an NIR dye used whilst the light-to-heat convertor (called hereafter a heater), an alkoxyamine (age.g., BlocBuilder-MA) is dissociated upon NIR light irradiation, starting the free-radical polymerization of methacrylates. In today's report, a novel approach is provided the very first time to dec