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Theoretical calculations reveal that the enhanced carrier transport properties are mainly attributed to the interlayer-induced coupling of the inorganic layers. Furthermore, the rigid structure of BDAPbI4 , resulting from the strong hydrogen bonds between the organic cations and the inorganic framework, will result in both low defect density and low ion migration, leading to superior carrier transport properties and detection performance.Mediated microbial electrosynthesis (MES) represents a promising strategy for the capture and conver