https://www.selleckchem.com/JAK.html
We propose electrospray-ionization (ESI) mass spectrometry as a robust and powerful method for the in situ analysis of carbanions. ESI mass spectrometry selectively probes the charged components of the sampled solution and, thus, is ideally suited for the detection of free carbanions. We demonstrate the potential of this method by analyzing acetonitrile solutions of 15 different carbon acids AH, whose acidities cover a range of 11.1 ≤ pKa(DMSO) ≤ 29.5. After treatment with KOtBu as a strong base, all but the two least acidic compounds were successfu
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