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A new assignment for photodetachment spectroscopy of AuCl2- is proposed where contribution of the 2Δg state is considered. The ground state of AgCl2 is calculated to be the 2B2 state of the C2v structure in scalar-relativistic (SR) calculations, while the SOC quenches the RTE and PJTE and the ground state becomes the 2Π3/2g state of the D∞h structure. As for the other molecules, the ground state is calculated to be the 2Πg state in SR cases, and the 2Π3/2g state with SOC. Our results indicate that a higher level electron correlation, large