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tories, and experts leading to an international standard for XPS intensity scale calibration.We introduce an estimation method of covariance matrices in a high-dimensional setting, i.e., when the dimension of the matrix, p, is larger than the sample size n. Specifically, we propose an orthogonally equivariant estimator. The eigenvectors of such estimator are the same as those of the sample covariance matrix. The eigenvalue estimates are obtained from an adjusted profile likelihood function derived by approximating the integral of the de
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