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© 2020 Wiley-VCH Verlag GmbH Co. KGaA, Weinheim.XOFs-type materials (X = M, C, S, i.e. Metal Organic Frameworks, Covalent Organic Frameworks and Supramolecular Organic Frameworks, respectively) share a common unifying feature mutual spatial orientation of constituting components is strictly directional and unchanging by design. Herein we illustrate an alternate design for porous architectures, as rigid joints constituted by coordinative (MOFs), covalent (COFs) or hydrogen donor/acceptor (SOFs) bonds, are replaced by supramolecula