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This ssNMR toolbox has the potential to provide important structural and dynamic information on chemical and physical modifications of biomaterials. STATEMENT OF SIGNIFICANCE Molecular characterisation of apatitic biomaterials by biophysical techniques is extremely difficult due to their complex and amorphous nature. It is, however, crucial to obtain such information if we want to understand their mechanical properties in relation to their physical state, for example their hydration levels. In this article we used a set of solid state NMR
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