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11 s. This work provides a facile fabrication of novel 3D carbon frameworks for supercapacitors with ultrafast charge/discharge rate and high energy-power density.Ceria-based heterostructure composite (CHC) has become a new stream to develop advanced low-temperature (300-600 °C) solid oxide fuel cells (LTSOFCs) with excellent power outputs at 1000 mW cm-2 level. The state-of-the-art ceria-carbonate or ceria-semiconductor heterostructure composites have made the CHC systems significantly contribute to both fundamental and applied science