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The thermal stability of cathode active materials (CAMs) is of major importance for the safety of lithium-ion batteries (LIBs). A thorough understanding of how commercially viable layered oxide CAMs behave at the atomic length scale upon heating is indispensable for the further development of LIBs. Here, structural changes of Li(Ni0.85Co0.15Mn0.05)O2 (NCM851005) at elevated temperatures are studied by in situ aberration-corrected scanning transmission electron microscopy (AC-STEM). Heating NCM851005 inside the microscope under vacuum condi