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Furthermore, we observed an additional 62% reduction in natural slicks, reducing global CO2 fluxes by 19% considering known frequency of slick coverage. From our observation, we identified surfactant concentrations with two different end-members which lead to an error in global CO2 flux estimation if ignored. © 2020 The Author(s).This paper is concerned primarily with constructive mathematical analysis of a general system of nonlinear two-point boundary value problem when an empirically constructed candidate for an approximate solution