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Our computational study not only provides a new class of 2D materials to enrich the material genome database, but also paves the way for practical applications of 2D III-V materials for electronic and optoelectronic devices.Post-synthetic modification of a dynamic carborane-based soft porous crystal (1 ⊃ DMF) by in situ polymerization of pyrrole to polypyrrole (PPy) provided a permanently porous MOF/polypyrrole hybrid composite material that did not show the dynamic behavior of the mother MOF. Apart from stability, the introduction of c
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