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5 wt% OPF-CNC showed the highest hydrophobicity (100.5 ± 0.7°) and has lowest amount of O via water contact angle and energy dispersive X-ray spectroscopy (EDX) analyses respectively, indicating lowest corrosion rate. An intelligent freshness indicator was developed by immobilizing anthocyanins of black carrot (ABC) within the starch matrix (total anthocyanins content of 10 mg/100 mL) to monitor freshness/spoilage of milk. The microstructural, spectral, swelling and solubility properties as well as color stability (as a function of time,