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However, racing unshod increased the relative risks of galloping and disqualification by 15%-35% in all seasons. Horses shod only on the hind hooves showed better performance than fully shod horses, without higher risks associated with competing unshod. © 2020 The Authors. Animal Science Journal published by John Wiley Sons Australia, Ltd on behalf of Japanese Society of Animal Science.Thiolate-protected nanoclusters with different charge states usually show similar structure frameworks but different electronic configuration