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Moreover, thermal modification was conducted to further prove the relationship between the basic sites and the DMDS adsorption. After thermal modification, the PAC with more basic sites and graphene structures was found to be more effective for DMDS adsorption. Overall, this study could offer guidance for water treatment plants with respect to the selection of PAC to solve the odor problems caused by various compounds (e.g., DMDS or 2-MI, and the modification of PAC, aiming at more efficient odor removal. This paper aims to elucidate