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Transition metal orthovanadates are emerging 2D materials for promising electrochemical energy storage applications. Facile hydrothermal method for nanocrystalline indium vanadate (InVO4) semiconducting materials' fabrication is economical because of its direct chemical synthesis. X-ray diffraction studies, field emission scanning electron microscope (SEM) images, transmission electron microscopy (TEM), and photoelectron X-ray spectrum are used to describe the semiconductor materials as synthesized. InVO4 microspheres have attracted a l