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The extraordinary ultralow friction could be attributed to the small contact area, high lubricant mass loading, efficient collection and storage of both abrasive debris and lubricant, and the self-orientation in the lubricating film. This work provides new insights into developing high-efficiency lubrication devices and aids in the industrial application of macroscopic superlubricity in future life.Two novel Ag(I) complexes containing synergistic pyridine and amidoxime ligands (Ag-DPAAO and Ag-PAAO) were first designed as complex monome
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