https://www.selleckchem.com/pr....oducts/avacopan-ccx1
Bulk electrolysis of 1, 2, or 3 at a potential of ca. -1.4 V vs E(Fc+/Fc) in the presence of TFA yields H2 with Faradaic yields close to 100%. A catalytic mechanism is proposed in which the pyridine moiety of a PN ligand acts as a pendant proton donor following opening of the chelate ring. Additional mechanisms may also operate, especially in the presence of high acid concentration where speciation changes.A novel gas-phase charge and mass manipulation approach is demonstrated to facilitate the mass measurement of high mass com
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