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Under the selected conditions, the method had a good linear response for the analytes in the range of 0.06-120 ng mL-1 for water and 1.5-1200 ng g-1 for honey samples. The limits of detections (S/N=3) fell in the range of 0.02-0.06 ng mL-1 for water and 0.5-1.5 ng g-1 for honey samples. The method recoveries for the analytes for spiked samples were in the range of 80.3-118%. The method can be applied for the determination of the NDZs from real samples.A new green method for trace level quantification of four herbicides, glyphosate (GLYP)