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Diffusion coefficients derived from the equation were in a range of 10-13 to 10-10 cm2/s and were dependent on the type of additive and solution.The description of the profiles of chromatographic peaks has been studied extensively, with a large number of proposed mathematical functions. Among them, the accuracy achieved with modified Gaussian models that describe the deviation of an ideal Gaussian peak as a change in the peak variance or standard deviation over time, has been highlighted. These models are, in fact, a family of function