https://www.selleckchem.com/pr....oducts/Ml-133-hcl.ht
Neutral palladium(ii) complexes [Pd(Rf)P-L)] (Rf = 3,5-C6Cl2F3, X = Cl, I, OTf) with P-P (dppe and dppf) and P-N (PPh2(bzN)) ligands have chelated structures in the solid-state, except for P-L = dppf and X = Cl, were chelated and dimeric bridged structures are found. The species present in solution in different solvents (CDCl3, THF, NMP and HMPA) have been characterised by 19F and 31P1H NMR and conductivity studies. Some [Pd(Rf)P-L)] complexes are involved in equilibria with [Pd(Rf)(solv)(P-L)]X, depending on the solvent and X. T
Like
Comment
Share
