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cycles, particularly in marine environments. This Account will discuss these findings and highlight future research directions and recommendations to better understand dust-climate interactions and the emerging role of biomass burning aerosol in marine biogeochemical cycles.A pulsed laser photolysis-photoionization mass spectrometer system has been employed to measure the rate constants of HCCO + O2 and HCCCO + O2 over the temperature range 243-423 K in 1.2-8.4 Torr of He or N2. Radicals of HCCO and HCCCO were produced by 193 nm ArF lase
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