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The MCLR reaction with free chlorine was strongly affected by temperature and the presence of DOM, while changes in ionic strength and alkalinity had little effect. Free chlorine in the presence of DOM, originating from both terrestrial and microbial sources, exhibited two-stage decay. The initial chlorine demand in the first 15 s of reaction can be determined by the dissolved organic carbon (DOC) concentration (initial chlorine demand = 1.8 × DOC), and the second-order rate constants for the later slower decay correlated well with SUVA
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