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Nano/microfibers are formed on areas having a morphology independent of the nature of the deposition substrate and displaying a wide tuning of properties that make the materials optoelectronically ideal for application in devices. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH Co. KGaA.DNA-templated self-assembly represents a rich and developing subset of supramolecular chemistry where useful self-assemblies tend to be programmed in a versatile fashion utilizing nucleic