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By tuning the chemistry regarding the polymer backbone and sidechains, we investigate how actual and mechanical properties of polymeric interphases influence Li electrodeposit morphology. It really is unearthed that an interplay between elasticity and diffusivity results in an optimum interphase thickness and that greater interfacial energy augments flexible stresses at a metal electrode to prevent out of jet deposition. These findings tend to be explained using linear security analysis of ele