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der reaction, from the catalyst polarizing the occupied π orbital of the dienophile away from the carbon atoms that form new bonds with the diene. This polarization of the occupied dienophile π orbital reduces the occupied orbital overlap with the diene and constitutes the ultimate physical factor responsible for the acceleration of the catalyzed process as compared to the analogous uncatalyzed reaction. We show that this physical mechanism is generally applicable regardless of the type of reaction (Diels-Alder and Michael addition react
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