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The effects of transition-metal ions that resulted in the reduction of PFRs when adsorbed on the Mnt-HA complex were as follows Fe3+ Zn2+ Cu2+ Mn2+, and this is in agreement with their redox capacity. Analyzing the induced generation of reactive oxygen species (ROS) and electrons on POM, it is found that halophenols and transition metal ions also affected this process under irradiation. These findings indicate that the photoformation of PFRs on POM could be a source of PFRs in aqueous environments and requires further att