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t the interpretation, for which the vibronic transitions that were previously assigned to a slightly bent structure of the first excited state needs to be revised and that a full rationalization of the PES spectra would require the explicit inclusion of the nuclear dynamical effects, beyond the Born-Oppenheimer (BO) approximation. From a methodological point of view, the relativistic EOM-IP-CCSD method results are highly accurate and capable of giving a well-balanced description of the anionic and neutral species, which is a key aspect for the int