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In float profiles, significant increases in Chl and phytoplankton carbon (C phyto) were detected below the mixed layer following episodic deep mixing events. These events pose a previously unrecognized source of new production below the mixed layer that can significantly boost the amount of carbon available for export to the deep ocean.Structurally diverse piperazine-based compounds hybrid with thiadiazole, isatin or with sulfur/nitrogen, functionalities were synthesized. The structures of the new compounds were established based on the