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Ion-exclusion chromatography (IEC) is categorized as a type of ion chromatography and is recognized as a simple and convenient water quality monitoring technology for a variety of ionic and nonionic substances. This review, mainly focusing on historical milestone studies by various authors, outlines the archives that concern the separation sciences and practical applications obtained from a variety of IEC modes used for water-quality monitoring as follows (1) early-developed IEC; (2) IEC using enhanced conductivity detection for weak ionic