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Differing from the wetting on a flat substrate, we show that the surface composition varying with temperature leads to a distinct wetting phenomenon in porous structures. The present findings provide an alternative interpretation for complete wetting and are expected to be exploited for designing more effectively and efficiently superhydrophilic structures.First principles simulations of carbon dioxide adsorbed on the ceria (CeO2) (111) surface are discussed in terms of structural features, stability, charge transfer, and vibrational mod