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We show that their contribution cannot be ignored, as particles smaller than less then 1 μm can contain up to 35% of the water+H2O2 extractable arsenic as methylated species, but only dimethylarsinate showed a clear seasonal trend throughout the year.A zinc metal-organic framework, i.e., Zn-MOF (Zn-DBC), with ca. 27% solvent-accessible void volume was synthesized from a rationally designed tetraacid based on sterically insulated dibenzo[g,p]chrysene core; the latter inherently features concave shapes. Due to rigidification of the fluoro