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This article is protected by copyright. All rights reserved.A 46-year-old man with no relevant medical history presented to the Emergency Department with a headache, retro-orbital pain, progressive proptosis and periorbital xanthelasmas. He denied bone pain nor any symptoms of diabetes insipidus. An ESR was 40 mm/hour and a CRP was 2.8 mg/dL. A non-contrast head CT demonstrated bilateral retro-orbital masses. This article is protected by copyright. All rights reserved.The adsorption of DPH in M 6.6 ZSM-5 (M = Na + , K + , Rb + , Cs + )