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We prepared a series of meso-thienyl boron-dipyrromethene (Bodipy) derivatives to investigate the spin-orbit charge transfer intersystem crossing (SOCT-ISC). The photophysical properties of the compounds were studied by steady-state and femtosecond/nanosecond transient absorption spectroscopy, as well as density functional theory (DFT) computations. Different from the meso-phenyl Bodipy analogues, the meso-thienyl Bodipy are weakly fluorescent. Based on femtosecond transient absorption and DFT computations, we propose that the torsion of
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