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Desorbed As speciation, FTIR and XPS researches indicated that As(III) was primarily adsorbed on top of Cu-Fe oxides followed by its oxidation to As(V). Within the oxidation reaction material oxides acted as catalysts and adsorbents, although the oxidant had been most likely oxygen mixed in answer. The discharge of large amount of chemicals from sectors to the environment has led to poisoning towards different living species. Therefore, risk assessment of those chemicals is impor