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On this basis, a summary about the hybridization of above 2D metal-free materials is presented, and the merits of 2D/2D hybrid systems are elaborated. Last, we wrap up this review with some summative remarks, covering understanding their own unique strengths and weaknesses by comparison and proposing the major challenges and perspectives in this emerging field.Microbial fuel cell (MFC) is an optimistic fuel cell technology that applies microorganism's biochemical catalytic activities in consuming organic substrate and produce electrici