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For validation of ab initio results, the fundamental vibration frequencies and absorption cross sections of the principal sulfur hexafluoride isotopologue are calculated, giving good agreement with cold (180 K) and room temperature (296 K) experimental spectra. Absorption cross sections calculated from our preliminary line list agree much better with these observations than the simulations using SF6 line-by-line lists constructed from effective models included in currently available spectroscopic databases.Considering that a molecu