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EG/MH/CaCO3 plays a synergetic effect on inhibiting the thermal-oxidative ageing of asphalt, and lowers the release number of harmful volatiles through the thermal-oxidative ageing after EG/MH/CaCO3 is added into asphalt in the proposed content of 10 wt.%. EG plays a synergistic part with MH and CaCO3 nanoparticles to prevent the sequence responses, suppressing the thermal-oxidative ageing of asphalt.Exposure to sunlight and experience of atmospheric air helps make the attention specially susce