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There is no coordination in 4 based on solid-state 13C NMR spectra, and only strong hydrogen bonds exist in the anion chains (VVO3)- and protonated arginines. 1 and 4 were fully characterized by elemental analysis, UV-vis, IR and solid-state 13C NMR spectroscopies, TG and X-ray structural analyses, and theoretical bond valence calculations (BVS). The conversions of glutamine, histidine and arginine occur spontaneously in a solution under ambient conditions.Lithium-rich phosphides have recently attracted considerable attention due to the

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