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The degradation pathways of p-CNB were proposed through GC/MS spectra. The acute toxicity, bioaccumulation factor and mutagenicity of identified intermediates were reduced after PEC degradation by g-C3N4/TNAs photoelectrodes. The Z-scheme g-C3N4/TNAs provided an efficient approach for simultaneous dechlorination and mineralization of refractory pollutants.A single exposure to glyphosate or antibiotic may facilitate cyanobacterial growth at currently reported concentrations due to hormesis. However, the influence of these contaminants on