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Once the internal pressure is properly taken into account, it becomes clear that CP cannot be less than CV for any substance at any temperature regardless of the sign of the thermal expansion coefficient of the substance.The development of low-cost and efficient electrocatalysts for oxygen evolution reaction (OER) is of great importance for producing hydrogen via water splitting. Metal-organic frameworks (MOFs) provide an opportunity for the facile preparation of high-efficiency OER electrocatalysts. In this work, we prepared iron-dope