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Although microbial reductive dehalogenation established fact when it comes to various other organohalides, no microbial reductive defluorination was recorded for perfluorinated substances except for a single, nonreproducible research on trifluoroacetate. Right here, we report on C-F relationship cleavage in 2 C6 per- and polyfluorinated compounds via reductive defluorination by an organohalide-respiring microbial community. The reductive defluorination had been demonstrated because of the launch