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The role of platinum on the room temperature NOx storage mechanism and the NOx desorption behavior of ceria was investigated by combining online FT-IR gas-phase analysis with in situ Raman and UV-vis spectroscopy. The type of pretreatment, leading to the presence of different platinum states (Pt0, and mixed Pt0/Pt2+), is shown to have a major effect on the NOx storage and desorption properties. Upon loading of ceria with platinum (1 wt%), NOx storage capacities decrease except for reductively pretreated Pt/CeO2, enabling new reaction p