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Oxidized aging due to the long-term exposure can significantly alter the sorption of pyrogenic chars (i.e., biochar, BC) towards antibiotics, which determined their fates in natural environments. In this study, the sorption of ciprofloxacin (CIP) on the oxidizing-aged BCs was studied linking the experimental thermodynamics and theoretical calculations. Results revealed that Q0 of CIP negatively correlated with their average site energies (Em), while pore-normalized Q0 on aged BCs were 2-6 folds higher than fresh BCs. From competitive so