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For surface problems, the nanothermodynamic approach is different, but equivalent to Gibbs' surface thermodynamics. It is however a general approach to the thermodynamics of small systems, and may therefore be applied to systems that do not have well defined surfaces. It is therefore desirable and useful to improve our basic understanding of nanothermodynamics.An increase in the global surface temperature and changes in urban morphologies are associated with increased heat stress especially in urban areas. This can be one of the contributing
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