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Despite the high theoretical energy density, lithium-sulfur (Li-S) batteries are currently facing two major problems, i.e., the shuttle of polysulfides and sluggish redox kinetics. Recent research has shown that electrocatalysts such as Pt and CoS2 can catalyze the polysulfide redox reaction and hence improve the kinetics and cycle performance of Li-S batteries. The current work demonstrates that a cheaper, lightweight and green alternative, i.e., titanium-deficient anatase TiO2 (TDAT) not only possesses a strong lithium polysulfide (Li