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The KSV values of 1 to CII), Cu(II), and PA are 6.0 × 104 M-1, 3.8 × 104 M-1, and 6.9 × 104 M-1, respectively. 1 exhibits high luminescent sensitiveness to PA even yet in the existence of other explosives.The multistep synthesis and characterization of brand new P═C analogues of olefins from easily obtainable starting materials is reported. Particularly, the phosphaalkenes TMOP-P═CPh2 (1a TMOP = 2,4,6-trimethoxyphenyl) and ArF-P═CPh2 [1b ArF = 2,6-bis(trifluoromethyl)phenyl] have already